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SPECTROFLUORIMETRIC DETERMINATION OF TERBIUM USING THE SYSTEM OF Tb(Ⅲ)-TPA

SPECTROFLUORIMETRIC DETERMINATION OF TERBIUM USING THE SYSTEM OF Tb(Ⅲ)-TPA
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摘要 Abstract: Terbium can form a stable binary chelate with terephthalic acid (benzene-1. 4-dicarboxylic acid(TPA) ) having a ratio of 1: 2 in aqueous solution in the pH range of 5~6. The maximum excitation and emission wavelengths are 260 nm and 545 nm for terbium chelate, respectively. The fluorescence intensity of terbium chelate remains stable in 8h with a relative standard deviation in the range of =4X. The rest of the lanthanide ions and the common foreign ions hardly interfere the determination. Abstract: Terbium can form a stable binary chelate with terephthalic acid (benzene-1. 4-dicarboxylic acid(TPA) ) having a ratio of 1: 2 in aqueous solution in the pH range of 5~6. The maximum excitation and emission wavelengths are 260 nm and 545 nm for terbium chelate, respectively. The fluorescence intensity of terbium chelate remains stable in 8h with a relative standard deviation in the range of =4X. The rest of the lanthanide ions and the common foreign ions hardly interfere the determination.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 1996年第5期453-456,共4页 中国化学快报(英文版)
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