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DETERMINATION OF HEAT EFFECT OF ANODIC PROCESS OF Ni<sub>3</sub>S<sub>2</sub>

DETERMINATION OF HEAT EFFECT OF ANODIC PROCESS OF Ni<sub>3</sub>S<sub>2</sub>
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摘要 DETERMINATIONOFHEATEFFECTOFANODICPROCESSOFNi_3S_2DETERMINATIONOFHEATEFFECTOFANODICPROCESSOFNi_3S_2¥Zhang,Hengzhong;Fang,Zheng... The electrowinning of Ni3S2 was designed to take place in a calorimeter in order to measurethe heat effect of the electrolysis with electrochemical calorimetry. The effect was determined un-der different cell voltuges ranging from 1.50 to 2. 16 V,and based on the data the heat effect ofthe anedic dissolution of Ni3S2 was figured out to be △aHm = 22. 4~99.0kJ.mol -1 (z=2)within the anode potentials 0.74~1.30 V(vs SCE).
出处 《中国有色金属学会会刊:英文版》 CSCD 1994年第2期14-17,共4页 Transactions of Nonferrous Metals Society of China
关键词 electrochcmical CALORIMETRY HEAT EFFECT anodic process POTENTIAL distributionNi3S2 electrochcmical calorimetry heat effect anodic process potential distributionNi3S2
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