Investigation on Oxidation-Reduction Properties of Some Fe-S and Mo-Fe-S Clusters

Investigation on Oxidation-Reduction Properties of Some Fe-S and Mo-Fe-S Clusters

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摘要 Oxidation-reduction properties of some Fe-S and Mo-Fe-S clusters have been studied by cyclic voltammetric measurement. It is indicated that there are some factors which affect the oxidation- reduction properties of clusters, of which are charge density of metal atom in cluster core, electron effect of ligands, charge and geometric configurations of the reactant particle, etc. Oxidation-reduction properties of some Fe-S and Mo-Fe-S clusters have been studied by cyclic voltammetric measurement. It is indicated that there are some factors which affect the oxidation- reduction properties of clusters, of which are charge density of metal atom in cluster core, electron effect of ligands, charge and geometric configurations of the reactant particle, etc.

作者 Zhang Hengbin, Xu Jiqing and Zhang Hongjie (Department of Chemistry, Jilin University, Changchun)

出处《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1990年第3期210-217,共8页 高等学校化学研究（英文版）

关键词 CLUSTER Redox Fe-S and Mo-Fe-S clusters Cluster, Redox, Fe-S and Mo-Fe-S clusters

分类号 O6 [理学—化学]

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Chemical Research in Chinese Universities

1990年第3期

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Investigation on Oxidation-Reduction Properties of Some Fe-S and Mo-Fe-S Clusters

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