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EFFECT OF OXYGEN CONTENTS ON OXYGEN POTENTIALS OF H_2O-H_2 AND H_2O-H_2-INERTS GAS MIXTURES

EFFECT OF OXYGEN CONTENTS ON OXYGEN POTENTIALS OF H_2O-H_2 AND H_2O-H_2-INERTS GAS MIXTURES
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摘要 By taking the effect of oxygen contents into account,a new set of formulae which represents the oxygen potentials of H_2O-H_2 and H_2O-H_2-inerts gas mixtures has been derived.Classi- cal representation is only a particular case of it.Some of the variables affecting equilibrium atmosphere when trace oxygen is present and optimum preparation of the gas mixtures to min- imize errors have been discussed.The reliability of some of previous equilibrium experiments under the oxygen potentials controlled by H_2O-H_2 or H_2O-H_2-inerts gas mixtures has also been criticized. By taking the effect of oxygen contents into account,a new set of formulae which represents the oxygen potentials of H_2O-H_2 and H_2O-H_2-inerts gas mixtures has been derived.Classi- cal representation is only a particular case of it.Some of the variables affecting equilibrium atmosphere when trace oxygen is present and optimum preparation of the gas mixtures to min- imize errors have been discussed.The reliability of some of previous equilibrium experiments under the oxygen potentials controlled by H_2O-H_2 or H_2O-H_2-inerts gas mixtures has also been criticized.
出处 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1990年第7期1-9,共9页 金属学报(英文版)
关键词 gas equilibration method H_2O-H_2 H_2O-H_2-inerts oxygen potential gas equilibration method H_2O-H_2 H_2O-H_2-inerts oxygen potential
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