Studies on Biomlmetic Oxidation for the Model Compound of Cytochrome P-450(IV)——Studies on Oxygenation of Cyclohexane Catalyzed by μ-Oxo-bis(5,10, 15,20-tetraphenylporphinato)iron(Ⅲ)

Chloro-（5,10,15,20-tetraphenylporphinato）iron（Ⅲ）(TPPFeCl)（A） used as a model compound of cytochrome P-450 to catalyze the monooxyenation of alkane is known, but the oxygenation of alkane catalyzed by μ-oxo-bis（5,10,15,20-tetraphenylporphinato）-iron（Ⅲ）(（TPPFe）;O)（B） has not been reported. The catalytic characteristics of B for the oxygenation of cyclohexane with PhIO in CH;Cl;and cyclohexane medium were studied. We found that B had a fairly good