摘要
Basic 2,2’-bipyridine (Pk_b 9.63) can catalyze the phase transfer of proton at the water/nitrobenzene interface. Investigations of chronopotentiometry with cyclic linear current-scanning and cyclic voltammetry show that the catalytic transfer behavior is closely related to pH of the aqueous phase. In this work, the theoretical expression of the transfer potential and current at different pHs has been deduced from the exper-
基金
Project supported by the Nitional Natural Science Foundation of China.