摘要
In 1982, A. B. P. Lever reported that μ-oxo-bis-phthalocyaninato iron （Ⅲ） （PcFe<sup>Ⅲ</sup>）<sub>2</sub>O photoreduced when irradiated under nitrogen, yielding PcFe（Ⅱ） and an oxoiron species. The mechanism of this photo-disproportionation remained in question. We have synthesized tetra-4-tert-amylphenoxy-phthalocyaninato-iron （Ⅱ）. It dissolves in benzene containing pyridine and absorbs oxygen in the air forming （PcFe<sup>Ⅲ</sup>）<sub>2</sub>O with absorption at 620 nm. Irradiation of a degassed solution of （PcFe<sup>Ⅲ</sup>）<sub>2</sub>·
