配合物氢键加合物的研究

STUDIES ON HYDROGEN BOND ADDUCTS OF CONPLEXES

本文报道合成也三种新的 Ni(salen)加合物,并以以热重,摩尔电导、磁化率和红外光谱等方法对加合物进行了性质表征。结果表明:在加合物中、Ni(salen)的平面四方形结构仍然保持、并不形成新的轴向配位键 Ni(salen)是通过酚氧和有机铵盐中的 N—H 形成氢键文章对加合物的可能结构也进行了探讨。

Three novel Ni(salen)complex adducts were reported.Their physicochemical proper- ties were characterized by IR.TG.Molar conductivity and Magnetic susceptibility measurements.The resuhs show that in these adducts the square planar structure if Ni(salen) is still retained and has no formation of any new axial bonding.The phenolic ox- ygens in the Ni(salen)interact with the protonated amino through hydro-gen bonding.