摘要
本文提出了一个描述含醇体系过量性质的修正拟化学溶液模型。该模型能关联各种温度下的h~Е,由较低温度下的h~Е关联预测较高温度下的h~Е。用该模型预测了24个含醇体系的汽液平衡,得到了令人满意的结果。
A modified quasi chemical solution model was developed to describe the excess properties of systems containing alcohols. The model is able to fit hE data at various temperatures and predict VLE data for systems containing alcohols.
出处
《南京工业大学学报(自然科学版)》
CAS
1989年第4期84-91,共8页
Journal of Nanjing Tech University(Natural Science Edition)
关键词
混合热
过量焓
过量自由焓
汽液平衡
excess enthalpy, heat of mixing, excess Gibbs free energy,VLE.