摘要
大多数物理化学书籍中,在讨论化学反应的标准自由焓变化△G°与平衡常数K的关系时,都没有提及体系中惰性物质的影响。实际上,这是不能不考虑的。本文就这一问题,提出了论证。
In most literature of physical chemistry, the influence of inert elements is neglected in the discription of the relationship between standard free enthalpy increment △G^o and equilibrium constant K. In many cases such a treatment is oversimplified. The influence of inert elements is discussed in the paper.
出处
《青岛理工大学学报》
CAS
1989年第2期55-61,共7页
Journal of Qingdao University of Technology
关键词
化学反应
惰性物质
平衡常数K
标准自由焓变化△G°
化学位μ
反应进度ξ
chemical reaction
inert element
equilibrium constant K
standand free enthalpy increment △G^0
chemical potential U
reaction extent