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ESTIMATION OF SULFUR SOLUBILITY AND PREDICTION OF SULFIDE LIQUID IMMISCIBILITY IN SILICATE MELTS

ESTIMATION OF SULFUR SOLUBILITY AND PREDICTION OF SULFIDE LIQUID IMMISCIBILITY IN SILICATE MELTS
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摘要 A set of 201 experimental data on solubility of sulfur in silicate melts was collectedfrom literature to formulate the changes of sulfur solubility as a function of bulk compo-sition of the melts and pressure, temperature, and the fugacity of oxygen and sulfur. Aregular solution model and a polynomial function have been put forward, from which sol-ubility of sulfur in natural silicate magmas can be estimated. Synthetic application of twomethods makes it possible to evaluate activity of FeS in a silicate melt, which will be po-tentially valuable for predicting immiscibility of sulfide liquid in magmatic processes. A set of 201 experimental data on solubility of sulfur in silicate melts was collectedfrom literature to formulate the changes of sulfur solubility as a function of bulk compo-sition of the melts and pressure, temperature, and the fugacity of oxygen and sulfur. Aregular solution model and a polynomial function have been put forward, from which sol-ubility of sulfur in natural silicate magmas can be estimated. Synthetic application of twomethods makes it possible to evaluate activity of FeS in a silicate melt, which will be po-tentially valuable for predicting immiscibility of sulfide liquid in magmatic processes.
作者 马鸿文
机构地区 Institute of Geology
出处 《Science China Chemistry》 SCIE EI CAS 1989年第10期1262-1270,共9页 中国科学(化学英文版)
基金 This research was supported in part by the Science Foundation grant under Prof. Chi Jishang from the National Education Committee.
关键词 MAGMA THERMODYNAMICS SULFUR SOLUBILITY SULFIDE IMMISCIBILITY magma thermodynamics sulfur solubility sulfide immiscibility
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