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较为宽松条件下水热合成铁酸铋粉体 被引量:11

Hydrothermal Synthesis of BiFeO_3 Powders under Loose Conditions
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摘要 BiFeO3是一种典型的单相磁电材料,室温下同时具有两种结构有序,即铁电有序倨里温度Tc=1100K)和G型反铁磁有序(尼尔温度Tn=650K),是少数同时具有铁电性和铁磁性的材料之一^[1-5],可以广泛应用于收音机、电视机、微波、通讯卫星、块状器件、磁泡器等领域, Bismuth ferrite(BiFeO3) powders were hydrothermally synthesized by using FeCl3·6H2O and BiCl3 as staring materials, NaOH as a mineralizer and NH4Cl as an additive. The results show that pure BiFeO3 powders can be synthesized under loose hydrothermal conditions of reaction temperature ranging from 140 to 230℃ and NaOH concentration ranging from 2 mol·L^-1 to 5 mol·L^-1. Moreover, the morphologies of the products can he controlled by changing the hydrothermal conditions.
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2009年第4期751-755,共5页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金(No.50772065)资助项目 陕西师范大学研究生培养创新基金(No.2008CXS035) 陕西师范大学实验室开放基金(No.8145)资助课题
关键词 水热法 BiFeO3粉末 多铁性材料 hydrothermal method BiFeO3 powders multiferroic material
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参考文献19

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同被引文献117

  • 1陈之战,施尔畏,元如林,郑燕青,李汶军,赵同荣.Coalescence of the crystallites under hydrothermal conditions (II) —— The morphology and stability energy calculation of cuprite[J].Science China(Technological Sciences),2003,46(4):423-431. 被引量:3
  • 2熊钢,杨卫明.磁电复合材料的研究进展[J].咸宁学院学报,2004,24(6):75-78. 被引量:6
  • 3路晓艳,刘玉岚,王彪.多重铁性材料的研究进展[J].材料导报,2007,21(3):17-20. 被引量:5
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  • 7Xu J H, Ke H, Jia D C, et al. Low-temperature synthe- sis of BiFe03 nanopowders via a sol-gel method [J]. J. Alloys Compd., 2009, 472:473-477.
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  • 9Ke H, Wang W, Wang Y B, et al. Factors controlling pure-phase nmltiferroie BiFe03 powders synthesized by chemical co-precipitation[J]. J. Alloys Compd., 2011, 509:2192-2197.
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