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正极材料LiNi_(0.5)Mn_(1.5)O_4的制备和性能 被引量：2

Preparation and performance of cathode material LiNi_(0.5)Mn_(1.5)O_4
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摘要 以Mn（CH3COO）2、Ni（CH3COO）2和CH3COOLi为原料，用流变相法制备了正极材料LiNi0．5Mn1．5O4。XRD测试表明：所得LiNio．5Mn1．504具有尖晶石结构。电化学性能测试表明：在750℃下焙烧6h制备的LiNio．5Mn1．504的电化学性能最佳。在3．5～4．9V以0．2C充放电，首次放比电容量为137．70mAh／g，第30次循环的放电比容量为135．75mAh／g。 Cathode material LiNi0.5 Mnl.5 04 was prepared by rheological method, Mn （CH3COO）2, Ni（CH3COO）2 and CH3COOLi were used as raw materials.XRD test showed that the obtained LiNi0.5 Mnl.504 had spinel structure. Electrochemical performance tests showed that the LiNi0.5Mn1.5O4calcined at 750 for 6 h had the optimun electrochemical performance. Its initial specific discharge capacity was 137.70 mAh/g when 0.2 C charge-discharge at 3.5 - 4.9 V, the specific discharge capacity at the 30th cycle was 135.75 mAh/g.
作者 张胜利 马利华 李良玉 宋延华
机构地区 郑州轻工业学院材料与化学工程学院 郑州轻工业学院现代教育技术中心
出处 《电池》 CAS CSCD 北大核心 2009年第2期91-93,共3页 Battery Bimonthly
基金 河南省科技攻关项目(0424210024)
关键词 尖晶石LiNi0.5Mn1.5O4 正极材料 流变相法 spinel LiNi0.5Mn1.5O4 cathode material rheological method
分类号 TM912.9 [电气工程—电力电子与电力传动]
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参考文献8

  • 1伊廷锋,胡信国,霍慧彬,高昆.5V锂离子电池尖晶石正极材料LiM_(0.5)Mn_(1.5)O_4的研究评述[J].稀有金属材料与工程,2006,35(9):1350-1353. 被引量：26
  • 2Fang H S, Wang Z X, Li X H, et al. Exploration of high capacity LiNi0.5Mn1.5O4 synthesized by solid-state reaction [ J ] . J Power Sources, 2006,153 ( 1 ) : 174 - 176.
  • 3Lee Y S,Sun Y K, Ota S, et al. Preparation and characterization of nano-crystalline LiNi0.5 Mn1.5O4 for 5 V cathode material by composite carbonate process [ J ] . Electrochem Commun, 2002, 4 (12) :989 - 994.
  • 4Fan Y K, Wang J M, Ye X B, et al. Physical properties and electrochemical performance of LiNi0.5 Mn1.5O4 cathode material prepared by a coprecipitation method[J] . Mater Chem Phys, 2007, 103(1):19-23.
  • 5Park S H, Oh S W, Kang S H, et al. Comparative study of different crystallographic structure of LiNi0.5Mn1.5O4-δ cathodes with wide operation voltage ( 2.0 - 5.0 V ) [ J ] . Electrochim Acta, 2007,52(25) :7 226 - 7 230.
  • 6陈宏浩,詹晖,朱先军,周运鸿.流变相法合成LiNi_(0.85)Co_(0.15)O_2的结构与电化学性能[J].化学学报,2005,63(11):1028-1032. 被引量：10
  • 7Zhong Q M,Arman B,Zhang M J, et al. Synthesis and electrochemistry of LiNixMn2-xO4[J] .J Electrochem Soc, 1997, 144 (1) :205 - 213.
  • 8Arira P, Popov B N, White R E. Electrochemical investigations of cobalt-doped LiMn2O4 as cathode material for lithium-ion batteries [J]. J Electrechem Soc, 1998,145(3) :807 - 815.

二级参考文献68

  • 1Koksbang, R.; Barker, J.; Shi, H.; Saidi, M. Y. Solid State Ionics 1996,84,1.
  • 2Desilvestro, J.; Haas, O. J. Electrochem. Soc. 1990,137,5C.
  • 3Thackeray, M. M.; Rossouw, M. H.; Gummow, R. J., Liles,D. C.; Pearce, K.; De Kock, A.; David, W. L. E; Hull, S.Electrochim. Acta 1993,38,1259.
  • 4Peng, Z.-S.; Wan, C.-R.; Jiang, C.-Y. J. Power Sources 1998,72,215.
  • 5Kweon, H. J.; Kim, G B.; Lim, H. S.; Nam, S. S.; Park, D.G.J. Power Sources 1999,83,84.
  • 6Arai, H.; Okada, S.; Sakurai, Y.; Yamaki, J. Solid State Ionics 1997,95,103.
  • 7Zhou, H.-H.; Ci, Y.-X.; Liu, C.-Y. Prog. Chem. 1998,10,85(in Chinese).
  • 8Li, W.; Reimers, J. N.; Dahn, J. R. Phys. Rev. B 1992,46,3236.
  • 9Amatucci, G G; Tarascon, J. M.; Klein, L. C. J. Electro-chem. Soc. 1996,143,1114.
  • 10Xia, Y.-Y.; Yoshio, M. J. Electrochem. Soc. 1996,143,825.

共引文献34

同被引文献44

  • 1徐晓莉,朱靖文,崔孝玲,毛丽萍,李世友.5V正极材料LiNi_(0.5)Mn_(1.5)O_4的制备及电化学性能研究[J].盐湖研究,2010,18(4):22-25. 被引量：4
  • 2陈宏浩,詹晖,朱先军,周运鸿.流变相法合成LiNi_(0.85)Co_(0.15)O_2的结构与电化学性能[J].化学学报,2005,63(11):1028-1032. 被引量：10
  • 3唐致远,杨光明,王倩.5V锂离子电池正极材料LiNi_(0.5)Mn_(1.5)O_4改性研究现状[J].材料导报,2007,21(6):35-38. 被引量：8
  • 4Xia Y Y,Zhou Y H, Yoshio M. Capacity fading on cycling of 4 V Li/LiMn2Oa cells[J] .J Electrochem Soc, 1997,144(8) : 2 593 - 2 600.
  • 5Kim J H, Yooh C S, Myung S T.Phase transitions in Lil-aNio.5 M nl.304 during cycling at 5 V [ J ]. Electrochem Solid-State Lett, 2004,7(7) : A216 - A220.
  • 6Sun Y Y, Yang Y F, Zhan H, et al.Synthesis of high power type LiMnl.sNio.5 04 by optimizing its preparation conditions [J]. J Power Sources,2010,195(13) :4 322 - 4 326.
  • 7Kim J H, Myurtg S T, Sun Y K. Molten salt synthesis of LiNio s Mn2.504 spinel for 5 V class cathode material of Li-ion secondary battery[J]. Electroehim Acta,2004,49(2) :219 - 227.
  • 8Sun Q, Li X H, Wang Z X, et al . Synthesis and electrochemical performance of spinel LiNio.5 M nt.5 04 prepared by solid-state reaction [ J] .Transactions of Nonferrous Metals Society of China, 2009,19(1):176- 181.
  • 9Fang H S, Wang Z X, Li X H, et al. Exploration of high capacity LiNio.sMnl.5 04 synthesized by solid-state reaction [J] .J Power Sources, 2006,153 ( 1 ) : 174 - 176.
  • 10Lafont U, Locati C, Borghols W J H, et al. Nanosized high voltage cathode material LiM go.05 Nio.45 Mn1.5 04 : structural, electrochemical and in situ investigation [ J]. J Power Sources, 2009, 189 ( 1 ) : 179- 184.

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二级引证文献11

电池
2009年 第2期

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