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多通道蛇形流场PEMFC内传递现象的数值模拟 被引量:2

Numerical simulation of transport phenomena in PEMFC with multi-channel serpentine flow fields
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摘要 电极板上的流场构型对质子交换膜燃料电池的流动特性和电池效率有重要的影响。为研究多通道蛇形流场设计质子交换膜燃料电池的局部流场、电流密度和组分浓度等的空间分布,应用作者前期发展的基于计算流体力学的三维稳态数学模型,对一个小型电池单体(电极面积大小为5.9cm×6.1cm)进行了详细的数值模拟,讨论和分析了该设计的流动特性和传输机理。结果表明:电池的电流密度分布比较均匀,阴极的压力损失要比阳极大得多,阳极氢的质量分数从流动入口到出口基本呈现增大趋势。 The flow field structure in the bipolar plates has an important effect on the flow characteristics and cell efficiency. In order to investigate spatial distribution of local gas flow field, species concentration and local current density in the PEMFC (proton exchange membrane fuel cell) with multi-channel serpentine flow field, a steady three-dimensional mathematical CFD based model presented in the author's previous paper was applied to conduct numerical study on a small-scaled single proton exchange membrane fuel cell (the electrode active area 5.9 cm × 6.1 cm) in this paper. The flow characteristics and transport mechanism were discussed and analyzed. It indicates that current density is uniform, the pressure loss in the cathode is much higher than that of anode, and the mass fraction of anode hydrogen increases from inlet towards outlet.
出处 《电源技术》 CAS CSCD 北大核心 2009年第4期245-248,共4页 Chinese Journal of Power Sources
基金 国家自然科学基金资助项目(50806068) 浙江省自然科学基金资助项目(Y106161) 教育部科学技术重点项目(207034) 能源清洁利用国家重点实验室开放课题(ZJUCEU2008001)
关键词 燃料电池(FC) 质子交换膜(PEM) 数值模拟 蛇形流场 fuel cell proton exchange membrane numerical simulation serpentine flow field
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参考文献13

  • 1BERNARDI D M,VERBRUGGE M W.A mathematical model of the solid-polymer- electrolyte fuel cell [J]. Journal Electrochem Soc, 1992, 139: 2477-2491.
  • 2NGUYEN T V, WHITE R E. A water and heat management model for proton-exchange- membrane fuel cells [J]. Journal Electrochem Soc, 1993, 140(8): 2178-2186.
  • 3GURAU V, LIU H T, SADIK K. Two-dimensional model for proton exchange membrane fuel cells [J]. AICHE Journal, 1998, 44(11): 2410-2422.
  • 4BERNING T, LU D M, DJILALI N. Three- dimensional computational analysis of transport phenomena in a PEM fuel cell [J]. Journal of Power Sources, 2002, 106(1): 284-294.
  • 5HU G, FAN J. Transient computation fluid dynamics modeling of a single proton exchange membrane fuel cell with serpentine channel [J]. Journal of Power Sources, 2007, 165(1): 171-184.
  • 6DUTTA S, SHIMPALEE S,VAN ZEE J W. Three-dimensional numerical simulation of straight channel PEM fuel cells [J]. Journal Appl Electrochem, 2000, 30: 135-146.
  • 7NATARAJAN D, NGUYEN T V.Three-dimensional effects of liquid water flooding in the cathode of a PEM fuel cell [J]. Journal of Power Sources, 2003, 115: 66- 80.
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  • 10DUTTA S, SHIMPALEE S, VAN ZEE J W. Numerical prediction of mass-exchange between cathode and anode channels in a PEM fuel cell [J]. International Journal of Heat and Mass Transfer, 2001, 44: 2029-2042.

二级参考文献12

  • 1BERNARDI D M, VERBRUGGE M W. A mathematical model of the solid-polymer-electrolyte fuel cell[J]. Journal of Electrochemical Society, 1992,139: 2477 - 2491.
  • 2SPRINGER T E, WILSON M S, GOTTESFELD S. Modeling and experimental diagnostics in polymer electrolyte fuel cells[J]. Journal of Electrochemical Society, 1993, 140(12): 513 - 3526.
  • 3ROWE A, LI X. Mathematical modeling of proton exchange membrane fuel cells[J]. Journal of Power Sources, 2001, 102: 82 - 96.
  • 4FULLER T F, NEWMAN J. Water and thermal management in solid-polymer-electrolyte fuel cells[J]. Journal of Electrochemical Society, 1993,140:1218 - 1225.
  • 5NGUYEN T V, WHITE R E. A water and heat management model for proton-exchange-membrane fuel cells[J]. Journal of Electrochemical Society, 1993, 140(8): 2178 - 2186.
  • 6YI J S, NGUYEN T V. An along-the-channel model for proton exchange membrane fuel cells[J]. Journal of Electrochemical Society, 1998, 145(4): 1149 - 1159.
  • 7GURAU V, LIU H, KAKAC S. Two-dimensional model for proton exchange membrane fuel cells[J]. AICHE Journal, 1998, 44: 2410 - 2422.
  • 8DUTTA S, SHIMPALEE S, VAN ZEE J W. Three-dimensional numerical simulation of straight channel PEM fuel cells[J]. Journal of Applicated Electrochemistry, 2000, 30: 135 - 146.
  • 9DUTTA S, SHIMPALEE S, VAN ZEE J W. Numerical prediction of mass-exchange between cathode and anode channels in a PEM fuel cell[J]. International Journal of Heat and Mass Transfer, 2001,44:2029 - 2042.
  • 10BERNING T, LU D M, DJILALI N. Three-dimensional computational analysis of transport phenomena in a PEM fuel cell[J]. Journal of Power Sources, 2002, 106: 284 - 294.

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