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Synthesis and fluorescence properties of cerium-KMgF_3 through a solvothermal process 被引量:1

Synthesis and fluorescence properties of cerium-KMgF_3 through a solvothermal process
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摘要 Phosphor of KMgF3:Ce^3+ is synthesized through solvothermal method at 180 ℃ and characterized by means of X-ray powder diffraction (XRD) and environment scanning electron microscopy (ESEM). X-ray photoelectron spectroscopy (XPS) is applied to the study of the energy band structure of KMgF3:Ce^3+ and confirms the oxygen content of the product is very low. The fluorescence spectra of the rare-earth ion-doped KMgF3 is investigated by the fluorescence spectrophotometer. In the emission spectra, there is a broadband emission with a maximum center located at 306 nm arising from d-f transition of Ce^3+ in the host. This will be useful for ultraviolet tunable lasers. Phosphor of KMgF3:Ce^3+ is synthesized through solvothermal method at 180 ℃ and characterized by means of X-ray powder diffraction (XRD) and environment scanning electron microscopy (ESEM). X-ray photoelectron spectroscopy (XPS) is applied to the study of the energy band structure of KMgF3:Ce^3+ and confirms the oxygen content of the product is very low. The fluorescence spectra of the rare-earth ion-doped KMgF3 is investigated by the fluorescence spectrophotometer. In the emission spectra, there is a broadband emission with a maximum center located at 306 nm arising from d-f transition of Ce^3+ in the host. This will be useful for ultraviolet tunable lasers.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2009年第1期106-110,共5页 中国化学快报(英文版)
基金 supported by the National Natural Science Foundation of China(No.50702057).
关键词 Solvothermal synthesis Ce^3+ ions KMGF3 LUMINESCENCE X-ray photoelectron spectroscopy (XPS) Solvothermal synthesis Ce^3+ ions KMgF3 Luminescence X-ray photoelectron spectroscopy (XPS)
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