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A mild,simple and efficient method for selectiveα-monobromination of 1,3-diketones and β-ketoesters using pyridinium bromochromate 被引量:2

A mild,simple and efficient method for selectiveα-monobromination of 1,3-diketones and β-ketoesters using pyridinium bromochromate
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摘要 Pyridinium bromochromate has been found to be a highly efficient and selective reagent for the α-monobromination of 1,3- diketones and β-keto-esters in the absence of base, Lewis acid, or other catalyst. The products were formed in high to excellent yields under mild reaction conditions and in short reaction times. Pyridinium bromochromate has been found to be a highly efficient and selective reagent for the α-monobromination of 1,3- diketones and β-keto-esters in the absence of base, Lewis acid, or other catalyst. The products were formed in high to excellent yields under mild reaction conditions and in short reaction times.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2009年第4期393-396,共4页 中国化学快报(英文版)
基金 support from the Research Council of Mazandaran University
关键词 α-Monobromination β-Ketoesters Pyridinium bromochromate 1 3-Diketones α-Monobromination β-Ketoesters Pyridinium bromochromate 1,3-Diketones
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