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Evaluation of attraction terms in equations of state on the prediction of solubility of some biomolecules in supercritical carbon dioxide

Evaluation of attraction terms in equations of state on the prediction of solubility of some biomolecules in supercritical carbon dioxide
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摘要 In the present work, effect of the attraction terms of four recently modified Peng-Robinson (MPR) equations of state on the prediction of solubility of caffeine, cholesterol, uracil and erythromycin was studied. The attraction terms of two of these equations are linear relative to the acentric factor and for the other two are exponential. It is found that the later show less deviation. Also interaction parameters for the studied systems are obtained and the percentage of average absolute relative deviation (%AARD) in each calculation is displayed. In the present work, effect of the attraction terms of four recently modified Peng-Robinson (MPR) equations of state on the prediction of solubility of caffeine, cholesterol, uracil and erythromycin was studied. The attraction terms of two of these equations are linear relative to the acentric factor and for the other two are exponential. It is found that the later show less deviation. Also interaction parameters for the studied systems are obtained and the percentage of average absolute relative deviation (%AARD) in each calculation is displayed.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2009年第4期501-505,共5页 中国化学快报(英文版)
关键词 Equation of state SOLUBILITY Supercritical carbon dioxide Biomolecules Equation of state Solubility Supercritical carbon dioxide Biomolecules
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参考文献11

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