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无卤磷系阻燃环氧树脂复合材料的制备及阻燃性能研究 被引量:2

The Preparation and the Property of Halogen-free Phosphorous Flame Retardant Epoxy Resin
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摘要 采用双酚A-双(磷酸二苯酯)分别与聚磷酸铵和纳米二氧化硅复配制备新型无卤阻燃环氧树脂(EP)材料。通过氧指数、垂直燃烧和锥形量热研究环氧树脂复合体系的阻燃性能。通过热失重和电镜扫描分析对比不同阻燃体系的热分解过程及燃烧炭层结构,推测阻燃机理。 The effect of flame retardant composed of bisphenol - A his(diphenyl) phosphate ester(BDP) and ammonium polyphosphate or nano -SiO2 on epoxy resin is investigated by limiting oxygen index( LOI), horizontal and vertical firing and cone calorimetry. The results indicate that BDP/SiO2 is more effective on the flame retardancy of epoxy resin than BDP/APP. The flame retardant mechanism is deduced by analyzing the thermal stability and the morphology of the residue of the flame retarded EP.
出处 《武警学院学报》 2009年第4期13-16,共4页 Journal of the Armed Police Academy
关键词 双酚A-双(磷酸二苯酯) 膨胀型阻燃剂 纳米二氧化硅 阻燃环氧树脂 bisphenol - A bis (dipenyl phosphate) intumscent flame retardant nano - silica flame retarded epoxy resin
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  • 1吴育良,王长安,许凯,陈鸣才.无卤磷系阻燃聚合物研究进展[J].高分子通报,2005(6):37-42. 被引量:39
  • 2郝建薇,熊燕兵,张涛.含磷环氧树脂的合成及阻燃研究[J].北京理工大学学报,2006,26(3):279-282. 被引量:37
  • 3唐煌.磷酸酯阻燃剂在PC/ABS合金中的应用[J].阻燃材料与技术,2006(4):7-10. 被引量:10
  • 4欧育湘,钟柳,刘进全,赵毅.无卤本质阻燃环氧树脂[J].高分子材料科学与工程,2006,22(5):240-244. 被引量:15
  • 5Duquesne S, Lefebvre J, Seeley G, et al. Vinyl acetate/ butyl acrylate copolymers Part 2: Fire retardancy using phosphorus-containing additives and monomers[J]. Polymer Degradation and Stability, 2004,85 (2) : 883-892.
  • 6Laoutid F, Ferry L, Lopez J M, et al. Red phosphorus/ aluminium oxide compositions as flame retardants in recycled poly ( ethylene terephthalate ) [ J ]. Polymer Degradation and Stability, 2003,82(2) :357-363.
  • 7Lira J C,Lee J H,Kwon I H. Flame retardant thermoplastic resin composition: US,6630524 [ P]. 2003-10-07.
  • 8Bradford L L, Pinzonl E, Williams B. et al. Polyurethane foam containing a blend of monomeric and oligomeric flame rctardants : US, 6262135 [ P ]. 2001-07-07.
  • 9Scrgei V Levchik, Edward D Weil. A review of recent progress in phosphorus-based flame retardants[ J ]. Journal of Fire Sciences, 2006,24:345-366.
  • 10Brand A,Seiz C,Engelmann J. Phosphor-nitrogen condensate ,method for producing the same and the use thereof as a flameproofing agent: EP, 1397418 ( A1 ) [ P]. 2002-12- 05.

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