[Cu_2(C_8H_7O_2N_2)_4(C_(12)N_2H_8)_2]的合成及晶体结构解析

Synthesis and Structure of [Cu_2(C_8H_7O_2N_2)_4(C_(12)N_2H_8)_2]

用苯乙酸做配体合成了苯乙酸铜的配合物,在配合物中,三个苯乙酸根参与配位,而一个苯乙酸根做为平衡离子存在于晶体中,邻啡罗啉提供两个N原子参与配位,形成铜的五配位双核配合物.分子内氢键和分子间氢键将分子连接成三维网状结构.

The compound Cu2 （C8 H7 O2 N2 ）4 （C12 N2 H8 ）2 is compoused by phenylacetate it is blue crystal, in Cu2 （C8 H7 O2 N2 ）4 （C12 N2 H8 ）2 three of the phenylaeetate anions acted as ligands, two phen offer N atoms. There are hydrogen bonds that make the units join together to form a long line.