期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

1,5,9-环十二碳三烯的合成 被引量：1

Synthesis　of　1,5,9-Cyclododecatriene
下载PDF
导出
摘要 研究了在３００Ｌ釜中丁二烯环化三聚生成１，５，９－环十二碳三烯的聚合工艺条件，考察了以甲苯和１，５，９－环十二碳三烯为溶剂的聚合反应行为，并对聚合反应的适宜温度以及最佳的催化剂配比范围进行了探讨。 ? Factors　such　as　solvent,temperature　and　molar　catalyst　ratio　influencing　1,3-butadiene　trimerization　to　1,5,9-cyclododecatriene　have　been　investigated　in　a　300　litre　reactor.The　results　showed　that　toluene　was　an　excellent　solvent.Optimal　temperature　and　molar　catalyst　ratio　have　also　been　investigated　and　discussed.
作者 胡顺民
机构地区 燕山石化公司合成橡胶厂研究所
出处 《石油化工》 CAS CSCD 北大核心 1998年第5期349-351,共3页 Petrochemical Technology
关键词 环化反应 三聚反应 CDT 合成 工程塑料 1,5,9-cyclododecatriene,1,3-butadiene,cyclization,trimerization
分类号 TQ322.3 [化学工程—合成树脂塑料工业]
  • 相关文献

同被引文献16

  • 1Zhao Wangyang,Huang Yajiang,Liao Xia,et al. The molecular structure characteristics of long chain branched polypropylene and its effects on non-isothermal crystallization and mechanical properties[J]. Polymer,2013,54(4):1455 - 1462.
  • 2Poon B,Rogunova M,Hiltner A,et al. Structure and properties of homogeneous copolymers of propylene and 1-hexene[J]. Macromolecules,2005,38(4):1232 - 1243.
  • 3Quijada R,Guevara J L,Galland G B,et al. Synthesis and properties coming from the copolymerization of propene with alpha-olefins using different metallocene catalysts[J]. Polymer,2005,46(5):1567 - 1574.
  • 4Rulhoff S,Kaminsky W. Synthesis and characterization of defined branched poly(propylene)s with different microstructures by copolymerization of propylene and linear ethylene oligomers (C n =26-28) with metallocenes/MAO catalysts[J]. Macromol Chem Phys,2006,207(16):1450 - 140.
  • 5Arnold M,Henschke O,Knorr J. Copolymerization of propene and higher α -olefins with the metallocene catalyst Et{Ind} 2 HfCl 2 /methylaluminoxane[J]. Macromol Chem Phys,1996,197(2):563 - 573.
  • 6Hackmann M,Repo T,Jany G,et al. Zirconocene-MAO-catalyzed homo- and copolymerizations of linear asymmetrically substituted dienes with propene:A novel strategy to functional ( co )poly( α -olefin)s[J]. Macromol Chem Phys,1998,199(8):1511 - 1517.
  • 7Walter P,Trinkle S,Lilge D,et al. Long chain branched polypropene prepared by means of propene copolymerization with 1,7-octadiene using MAO-activated rac -Me 2 Si(2-Me-4-Phenyl-Ind) 2 ZrCl 2 [J]. Macromol Mater Eng,2001,286(5):309 - 315.
  • 8Kaminsky W,Derlin S,Hoff M. Copolymerization of propylene and norbornene with different metallocene catalysts[J]. Polymer,2007,48(25):7271 - 7278.
  • 9Boggioni L,Zampa C,Ravasio A,et al. Propene-norbornene copolymers by C 2 -symmetric metallocene rac -Et(Ind) 2 ZrCl 2 :Influence of reaction conditions on reactivity and copolymer properties[J]. Macromolecules,2008,41(14):5107 - 5115.
  • 10Radeglia R,Poleschner H,Haufe G. NMR spectroscopic characterization of ZE isomers of cyclododeca-1,5,9-triene[J]. Magn Reson Chem,1993,31(12):1054 - 1056.

二级引证文献2

石油化工
1998年 第5期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部