新型钌系聚吡咯络合物的合成、结构和表征

Synthesis,Structure and Characterization of a Novel PolypyrroleComplex Doped by Ru

采用电化学方法成功地合成了钌掺杂聚吡咯络合物（ＰＰＲＵＣ），ＰＰＲＵＣ是一种很稳定的非晶态络合物，合成掺杂聚吡咯络合物来改变催化剂的存在形态，使催化剂与反应物和产物很好地分离。用物理吸附仪对ＰＰＲＵＣ进行了比表面积和孔容等的测定，用红外和电子能谱对ＰＰＲＵＣ进行了表征，用元素分析仪测定了ＰＰＲＵＣ含Ｃ、Ｎ、Ｈ的比。根据测定结果和文献报道推断了ＰＰＲＵＣ的基本结构。

A novel Ru doped polypyrrole complex(PPRUC) was successful synthesized by electrochemistry method. The PPRUC is a stable incrystal complex. The complex doped ploypyrrole can change the existing state of the catalyst, and make catalyst apart from product and reactant. The PPRUC was characterized and determined by physical sorption instrument, IR, electron microscopy,electron energy spectrum, elemental analysis. The structure of PPRUC was estimated.