摘要
烷基芳香烃氧化反应的研究,直接关系着石油化工工业下游产品的开发。烃类物质的氧化反应均在不同的催化剂和氧化剂存在下进行。近年来,一些新试剂如含钌化合物、杂多金属酸盐等已被用于烃类物质氧化反应的研究。对一些经典的催化剂和氧化剂如含钴(Ⅱ)、含铁(亚铁)以及铬化物、锰化物等也作了进一步的深入研究。其中有的试剂体系在烃类物质的氧化反应中显示出很高的转化率和选择性,因而具有一定的应用价值。现将上述文献整理出来供大家参考。
The study of the oxidation reaction of alkylaromatics is directiy related to the development of the following products in petrochemical industry. The oxidation of hydrocarbons is carried out in the presence of different catalysts and oxidative agents. In the last few years. Some new chemical agents, for example, the compounds containing ruthenium polyoxometalates and heteropolyanion have been used in the study of oxidation hydrocarbons, some classic catalysts and oxidation agents, such as compounds containing chrome, manganese etc. have also been further researched. Some of the agents systems show high conversion rate and selectivity in the oxidation reaction for hgdrocarbons, hence they have a relatively high value in application. Now the above articles have been rearranged for the readers′ reference.
出处
《石油化工高等学校学报》
CAS
1998年第2期40-46,共7页
Journal of Petrochemical Universities
关键词
烷基芳香烃
氧化
催化氧化
芳香烃
Ethylbenzene
1-Phenylethanone
Alkylaromatic hydrocarbon
Benzylic oxidation
Catalyst-oxidation