杂环端基开链化合物的合成及其与Cu(Ⅱ)的作用

Synthesis of Mixed Donor Acyclic Ligands Bearing Heterocyclic Moieties as Terminal Groups: Reaction and Properties of Their Copper(Ⅱ) Complexes

利用８－巯基喹啉钠盐与２－氯甲基吡啶和多甘醇二溴化物反应合成了３个带吡啶或喹啉配位端基Ｓ，Ｏ杂开链化合物，作为小分子模拟铜蓝蛋白模型化合物的潜在配体，并初步探讨了它们与过渡金属离子的配位作用．

Three mixed donor acyclic ligands bearing heterocyclic moieties as terminal groups has been prepared by the reaction of 8 mercaptoquinoline sodium salt with 1, 5 dibromo 4 oxapentane, 1, 8 dibromo 3, 6 dioxaoctane and 2 chloromethylpyridine as the low molecular weight blue copper protein modeling compounds. The reaction and properties of their copper(Ⅱ) complexes have been primarily investigated.