摘要
用阳电、阴电的部件做的分子的电子状态源于在共有原子价配置和离子的配置之间的干扰。这个工作在象李 <SUB>2</SUB 那样的小分子显示出这些离子共有原子价的政变石楠的复杂方面 > H,李 <SUB>2</SUB > F,和李 <SUB>4</SUB > F。到金属簇上或在金属表面上的 electrophilic 分子的吸附的这类分析的延期应当导致极端地新的解释观察了物理、化学的性质。
The electronic states of molecules made of electropositive and electronegative components result from the interference between the covalent configurations and the ionic configurations. This work shows complex aspects of these ionic-covalent couplings in small molecules such as Li2H, Li2F, and Li4F. The extension of this type of analysis to the adsorption of the electrophilic molecules on the metal clusters or on the metal surfaces is supposed to lead to a radically new interpretation of the observed physical and chemical properties.
关键词
表面吸附
电子转移
共价构型
离子构性
电子态
Surface adsorption, Electron transfer, Covalent configuration, Ionic configuration, Electronic state