摘要
A convenient and selective catalytic method for the sulfoxidation of aliphatic and aromatic sulfides by treatment of NH4NO3, silica sulfuric acid, wet SiO2 (50% w/w) and a catalytic amount of KBr in CH2Cl2 at room temperature was developed. Many sulfides can be selec-tively oxidized at room temperature in good to excellent yields. The reaction proceeds without over-oxidation to sulfones under mild conditions.
A convenient and selective catalytic method for the sulfoxidation of aliphatic and aromatic sulfides by treatment of NH4NO3, silica sulfuric acid, wet SiO2 （50% w/w） and a catalytic amount of KBr in CH2Cl2 at room temperature was developed. Many sulfides can be selec-tively oxidized at room temperature in good to excellent yields. The reaction proceeds without over-oxidation to sulfones under mild conditions.
出处
《催化学报》
SCIE
EI
CAS
CSCD
北大核心
2009年第4期273-275,共3页
基金
Supported by the Center of Excellence of Development of Chemical Methods(CEDCM)of Bu-Ali Sina University,Iran.
关键词
硝酸铵
硫化物
化学反应
催化剂
sulfide
sulfoxide
chemoselectivity
ammonium nitrate
potassium bromide
silica sulfuric acid
