摘要
The title compound (E)-N1,N4-bis(2,3,4-trimethoxy-6-methylbenzylidene) butane- 1,4- diamine (C26H36N2O6, Mr = 472.57) was synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to triclinic, space group C2/c with a = 36.102(4), b = 5.6620(11), c = 13.015(2)A,β = 105.491 (2)°, V = 2563.7(7)A3, Z = 4, Dc = 1.224 g/cm3, 2 = 0.71073 A,μ(MoKα) = 0.087 mm^-1, F(000) = 1016, the final R = 0.0456 and wR = 0.1257 for 2255 observed reflections with I 〉 2σ(I). X-ray diffraction analysis reveals that the molecule adopts an E configuration about the central C=N functional bond. The phenyl rings of two 2,3,4-trimethoxy-6-methylbenzaldehyde groups are parallel by symmetry. The molecules are linked through π-π and C-H…π stacking interactions and C-H…O hydrogen bonding interactions. The title compound possesses moderate antibacterial activity.
The title compound (E)-N1,N4-bis(2,3,4-trimethoxy-6-methylbenzylidene) butane- 1,4- diamine (C26H36N2O6, Mr = 472.57) was synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to triclinic, space group C2/c with a = 36.102(4), b = 5.6620(11), c = 13.015(2)A,β = 105.491 (2)°, V = 2563.7(7)A3, Z = 4, Dc = 1.224 g/cm3, 2 = 0.71073 A,μ(MoKα) = 0.087 mm^-1, F(000) = 1016, the final R = 0.0456 and wR = 0.1257 for 2255 observed reflections with I 〉 2σ(I). X-ray diffraction analysis reveals that the molecule adopts an E configuration about the central C=N functional bond. The phenyl rings of two 2,3,4-trimethoxy-6-methylbenzaldehyde groups are parallel by symmetry. The molecules are linked through π-π and C-H…π stacking interactions and C-H…O hydrogen bonding interactions. The title compound possesses moderate antibacterial activity.
基金
supported by the Natural Science Foundation of Shandong Province (No. Y2007B61)