摘要
在基础物理化学的基础上,用热力学方法讨论了不可逆电池过程的功和热,给出了计算公式,并推广到无副反应的电解过程。
Based on physicochemistry,work and heat in the processes of irreversible cell were discussed by thermodynamical method.The formula was derived,and it was popularized to the process of electrolysis which with no sidereaction.