金属-有机骨架羧酸C_(21)H_(15)CoN_2O_4的合成及晶体结构

Hydrothemal Synthesis and Crystal Structure of Metal-Organic Framework Compound C_(21)H_(15)CoN_2O_4

采用水热合成法合成了化合物C21H15CoN2O4,并测定了其晶体结构.化合物晶体属于三斜晶系,P-1空间群,晶体学参数为:a=0.8709(15)nm,b=1.0111(18)nm,c=1.1836(2)nm,α=68.298(3)°,β=82.913(3)°,γ=78.405(3)°,V=0.9472(3)nm3,Z=2,Dc=1.467g/cm3.

The title compound of C21H15CoN2O4 is synthesized by hydrothermal method. Its crystal structure is determined by single crystal X-ray diffraction. The crystal belongs to triclinic system with space groud of P - 1 and the unite parameters ： a=0.8709（15）nm,b=1.0111（18）nm,c=1.1836（2）nm,α=68.298（3）°,β=82.913（3）°,γ=78.405（3）°,V=0.9472（3）nm^3,Z=2,Dc=1.467g/cm^3.