期刊文献+

BA-St-MAA复合乳液共聚合动力学和成核机理的研究 被引量:3

THE KINETICS AND NUCLEATION OF EMULSION COPOLYMERIZATION OF BUTYL ACRYLATESTYRENEMETHACRYLIC ACID WITH MIXED EMULSIFIERS
下载PDF
导出
摘要 研究了丙烯酸丁酯(BA)-苯乙烯(St)-甲基丙烯酸(MAA)体系在复合乳化剂存在下的乳液共聚合行为,比较了不同乳化剂浓度对乳液聚合动力学的影响,还从粒子大小、形态、分布以及羧酸分布和胶膜性质等方面探讨了复合乳液的成核机理。 Behaviors of BAStMAA emulsion copolymerization using complex emulsifiers system conprising anionic emulsifier and nonionic emulsifier were studied. The effects of different emulsifier content on copolymerization kinetics were investigatied. Particle size and distribution analysis of latexs with drawn during course of the reaction was completed byAutosizer'. Particle size, morphology, distribution, carboxylic acid distribution and latexs film properties provided important information for the study on nucleation mechanism of copolymerization with mixed emusifiers.
机构地区 湖北大学化学系
出处 《高分子材料科学与工程》 EI CAS CSCD 北大核心 1998年第2期47-50,共4页 Polymer Materials Science & Engineering
关键词 乳液聚合 复合乳液 成核 动力学 BA-St-MAA乳液 emulsion polymerization, mixed emulsifiers, nucleation mechanism
  • 相关文献

参考文献5

  • 1程时远,高分子通报,1991年,3期,135页
  • 2大森英三,丙烯酸酯及其聚合物,1987年,140页
  • 3Chen S A,J Polym Sci Polym Chem,1985年,23卷,2615页
  • 4李克友,乳液聚合,1985年,40页
  • 5Hen J J,Colloid Interface Sci,1974年,49卷,3页

同被引文献20

  • 1刘金辉,李效玉,焦书科.以阳离子乳化剂进行丙烯酸丁酯-苯乙烯乳液共聚的动力学研究[J].高分子学报,1995,5(4):472-476. 被引量:50
  • 2洪啸吟 冯汉保.涂料化学[M].科学出版社,2000,1.181.
  • 3OPERA S, VALD S, STACIU A. Epoxy urethane acrylate[J]. Eur. Polym. J., 2000, 36(2): 373-378.
  • 4SMITH W V, EWART R H. Kinetics of emulsion polymerization [J]. J. Chem. Phys., 1948, 16(6): 592-599.
  • 5OTTEWILL R H. Emulsion polymerization [ M ]. PIIRMA I ed. New York: Academic Press, 1982: 1-47.
  • 6ELISEEVA V I, WANCHEY S S, KUCHANOV S I, et al. Emulsion polymerization and its applications in industry[M]. New York: Consultants Bureau, 1981: 38.
  • 7TOSSOT I,REMOND J P, LEFEBVRE F, et al. SiOH- funetionalized polystyrene latex, a step toward the synthesis of hollow silica nanoparticles [ J ]. Chem. Mater. , 2002, 14 (3) :1325-1331.
  • 8CAPEK I, JURANICOVA V, BARTON J, et al. Microemulsion radical polymerization of alkyl acrylates[J]. Polym. Int., 1997, 43: 1-7.
  • 9XU X L, FEI B, ZHANG Z C, et al. Polymerization of butyl acrylate in anionic mieroemulsion[J]. J. Polym. Sci. Part A. Polym. Chem., 1996, 34: 1657-1661.
  • 10CHERN C S, TANG H J. Microemulsion polymerization kinetics and mechanic[J]. J. Appl. Polym. Sci., 2005, 97: 2005-2013.

引证文献3

二级引证文献6

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部