摘要
采用浓度为10%的氢氟酸(HF)刻蚀6H-SiC单晶片,研究了HF刻蚀时间对Ni/6H-SiC接触性质的影响.经24h刻蚀的SiC基片在溅射Ni层后,其接触表现良好线性的电流-电压(I-V)曲线.低于这个腐蚀时间的接触具有明显的势垒,但在大于1000℃快速退火后,也得到了良好线性的I-V曲线.X射线衍射(XRD)和俄歇能谱(AES)深度元素分析表明Ni2Si和C是快速退火后的主要产物.XRD和低能反射电子能量损失谱表明表层的C元素是以非晶态存在.通过研究高温快速退火下元素的互扩散及HF与SiC表层反应机理,发现SiC表面富碳层是这两种方法形成欧姆接触的关键因素.
The effect of hydrofluoric acid (HF) etching time on Ni/6H-SiC ohmic contacts was investigated. The as-deposited Ni/6H- SiC contacts prepared by 6H-SiC substrates which have been subjected to different HF etching time have different I-V characteristics. For SiC substrates etched for less than 12 hours, the contacts were rectifying, and excellent linear curves were observed after high temperature thermal annealing. X-ray diffraction, Auger electronic spectroscopy and low-energy reflection electron energy loss spectroscopy showed that Ni2 Si and amorphous C were the main reaction products after annealing. For SiC substrate etched for 24 hours, the as-deposited Ni/6H-SiC contact was ohmic. The carbon-enriched layer (CEL) on the SiC surface plays an important role in the formation of ohmic contact.
出处
《物理学报》
SCIE
EI
CAS
CSCD
北大核心
2009年第5期3443-3447,共5页
Acta Physica Sinica
基金
国家高技术研究发展计划(863)(批准号:2006AA03A146)
中国科学院知识创新项目(批准号:KGCX2-YW-206)
上海自然科学基金(批准号:06ZR14096)
高性能陶瓷和超微结构国家重点实验室开放基金(批准号:SKL200810SIC)资助的课题~~
关键词
欧姆接触
SIC
富碳层
互扩散
ohmic contact, silicon carbide, carbon-enriched layer (CEL), mutual diffusion