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悬浮型光催化纳滤膜反应器处理H酸溶液工艺中操作压力变化的机理研究:实验部分 被引量:1

Systematic studies on influencing mechanisms of TMP changs of suspended photocatalytic nanofiltration membrane reactor for treatment of H-acid aqueous solutions: experimental part
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摘要 首次通过系列黑暗条件下的膜分离空白试验对悬浮型光催化纳滤膜反应器中耦合分离膜操作压力的变化机理进行研究。为了从根本上揭示悬浮型光催化纳滤膜反应器中引起耦合分离膜操作压力规律性变化以及不同初始操作压力条件下导致变化规律明显差异性的根本原因,分别进行三组黑暗条件下的膜分离对比试验,考察不同膜分离过程中膜分离操作压力的变化规律、变化幅度和变化速度。结果表明,在不同的初始操作压力条件下,由于待分离的污染物种类、性质、组分和浓度的差异导致纳滤膜分离操作压力的变化规律存在根本性变化。 The systematic studed on influencing mechanisms of changs in TMP (transmembrane pressure) of suspended nanofihration membrane reactor for treatment of H-acid aqueous solutions were innovatively performed through the series of three blank membrane separation experiments under the dark conditions, aiming at elucidating the corresponding mechanism of transmembrane pressure change during suspended photocatalytic nanofiltration membrane reactor for removal of H-acid substrate in terms of the changing behaviors, changing ranges and rates. Moreover, all the four blank membrane separation experiments without UV illumination indicated that very different changing behaviors, changing ranges and rates of transmembrane pressure could be observed under the three different given initial value of 5.5,4.0 and 3.0 bar, which could be dedicated to the significant differences in the organic species, components, properties and concentrations of the employed pollutants among the stated four membrane separation experiments in the study.
作者 刘军 高冠道
出处 《化学工程师》 CAS 2009年第5期1-4,36,共5页 Chemical Engineer
基金 国家自然科学基金项目"仿生光催化剂的合成及其对有毒有机废水的降解研究"(20803036) 南开大学创新基金"难降解有毒有机废水治理及资源化技术应用研究"(ZB0698) 高等学校科技创新工程重大项目培育资金项目(707011)
关键词 光催化氧化 纳滤膜分离 耦合工艺 H酸 过膜压力 变化机理 photocatalytic oxidation process nanofihration membrane separation coupled technique H- acid transmembrane pressure change mechanisms
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参考文献18

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二级参考文献48

共引文献21

同被引文献12

  • 1张爱勇,肖羽堂,吕晓龙,高冠道.光催化膜反应器在污废水处理中的应用研究进展[J].现代化工,2006,26(10):25-30. 被引量:12
  • 2Sze Sze Chin,Ken Chiang,Anthony Gordon Fane.The stability of polymeric membranes in a TiO2 photocatalysis process[J].Journal of Membrane Science,2006,275:202-211.
  • 3S.Horikoshi,N.Serpone,Y.Hisamatsu,H.Hidaka,Photocatalyzed degradation of polymers in aqueous semiconductor suspensions[J].Photooxidation of solid polymer:TiO2-blended poly (vinyl chloride) film,Environ.Sci.Technol.,1998,32:4010.
  • 4U.Gosenhues,Influence of titanium dioxide pigments on the photodegradation ofpoly(vinyl chloride)[J].Polym.Degrad.Stabil.,2000,68:185.
  • 5Hyeok Choi,Elias Stathatos,Dionysios D.Dionysiou.Sol-gel preparation of mesoporous photocatalytie TiO2 films and TiO2/Al2O3 composite membranes for environmental applications[J].Applied Catalysis B:Environmental,2006,63:60-67.
  • 6Yanbin Meng,Xia Huang,Qunhao Yang,Yi Qian,Nobuhiko Kuboto,Sakae Fukunaga.Treatment of polluted river water with a photocatalytic slurry reactor using low-pressure mercury lamps coupled with a membrane[J].Desalination,2005,181:121-133.
  • 7Tusnelda E.Doll,Fritz H.Frimmel.Cross-flow microfiltration with periodical back-washing for photocatalytic degradation of pharmaceutical and diagnostic residues-evaluation of the long-term stability of the photocatalytic activity of TiO2[J].Water Research,2005,39:847-854.
  • 8Raffaele Molinari,Leonardo Palmisano,Enrico Drioli,Mario Schiavello.Studies on various reactor configurations for coupling photocatalysis and membrane processes in water purification[J].Journal of Membrane Science,2002,206:399-415.
  • 9Teng Zheng,Huang Jian Yuan,Fujita Kenji,Takizawa Satoshi.Manganese removal by hollow fiber micro-filter[J].Membrane separation for drinking water.Desalination,2001,139:411-418.
  • 10Pierre Le-Clech,Eun-Kyung Lee,Vicki Chen.Hybrid photocatalysis/membrane treatment for surface waters cantaining low concentrations of natural organic matters[J].Water Research,2006,30:323-330.

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