摘要
首次通过系列黑暗条件下的膜分离空白试验对悬浮型光催化纳滤膜反应器中耦合分离膜操作压力的变化机理进行研究。为了从根本上揭示悬浮型光催化纳滤膜反应器中引起耦合分离膜操作压力规律性变化以及不同初始操作压力条件下导致变化规律明显差异性的根本原因,分别进行三组黑暗条件下的膜分离对比试验,考察不同膜分离过程中膜分离操作压力的变化规律、变化幅度和变化速度。结果表明,在不同的初始操作压力条件下,由于待分离的污染物种类、性质、组分和浓度的差异导致纳滤膜分离操作压力的变化规律存在根本性变化。
The systematic studed on influencing mechanisms of changs in TMP (transmembrane pressure) of suspended nanofihration membrane reactor for treatment of H-acid aqueous solutions were innovatively performed through the series of three blank membrane separation experiments under the dark conditions, aiming at elucidating the corresponding mechanism of transmembrane pressure change during suspended photocatalytic nanofiltration membrane reactor for removal of H-acid substrate in terms of the changing behaviors, changing ranges and rates. Moreover, all the four blank membrane separation experiments without UV illumination indicated that very different changing behaviors, changing ranges and rates of transmembrane pressure could be observed under the three different given initial value of 5.5,4.0 and 3.0 bar, which could be dedicated to the significant differences in the organic species, components, properties and concentrations of the employed pollutants among the stated four membrane separation experiments in the study.
出处
《化学工程师》
CAS
2009年第5期1-4,36,共5页
Chemical Engineer
基金
国家自然科学基金项目"仿生光催化剂的合成及其对有毒有机废水的降解研究"(20803036)
南开大学创新基金"难降解有毒有机废水治理及资源化技术应用研究"(ZB0698)
高等学校科技创新工程重大项目培育资金项目(707011)
关键词
光催化氧化
纳滤膜分离
耦合工艺
H酸
过膜压力
变化机理
photocatalytic oxidation process
nanofihration membrane separation
coupled technique
H- acid
transmembrane pressure
change mechanisms