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二核钒配合物NH_4[Gd(H_2O)_9][(VO)_2(μ_2-O)(nta)_2]的合成

Synthesis of Dinuclear Vanadum Complex NH_4[Gd(H_2O)_9][(VO)_2(μ_2-O)(nta)_2]
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摘要 以偏钒酸铵、氮三乙酸、氧化钆为原料,合成了新型钆修饰的二核钒配合物NH4[Gd(H2O)9][(VO)2(μ2-O)(nta)2][1,H3(nta)=氮三乙酸],其结构经UV,IR和元素分析表征。热稳定性测量显示,1在80℃以下能稳定存在。 A novel dinuelear vanadum complex, NH4 [ Gd ( H2O)9 ] [ (VO)2 (μ2-O) ( nta)2 ] [ 1, H3 (nta) = nitrilortiaeetie acid ] , was synthesiszed from ammonium metavanadate, nitrilortiaeetie acid and Gadolinium oxide. The structure was characterized by UV, IR and elemental analysis. The testing results showed that 1 exhibited good thermal stability with decomposition temperature above 80℃.
出处 《合成化学》 CAS CSCD 北大核心 2009年第3期368-369,372,共3页 Chinese Journal of Synthetic Chemistry
基金 安徽高校省级自然科学研究重点资助项目(KJ2007A014) 合肥学院粉体与能源材料重点实验室资助项目
关键词 二核配合物 氮三乙酸 合成 Vanadum dinuclear complex nitrilotriacetie acid gadolinium synthesis
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参考文献7

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