4,5-二对氯苄硫基-1,3-二硫杂环戊烯-2-硫酮配体的合成及其结构表征

Synthesis of 4,5-di-(p-chloride benzylthio)-1,3-dithiole-2-thione Ligand and Identify the Structure

由两种途径[dmit的钠盐与卤代物反应和(dmit)2Zn(NBu4)2直接与卤代物反应]合成4,5-二对氯苄硫基-1,3-二硫杂环戊烯-2-硫酮配体,对两种途径的优缺点做了比较和分析,用IR谱图简单的表征了其结构.

In two ways,sodium salt of dmit react with halide and（dmit）2Zn（NBu4）2 directly react with halide,to yield 4,5-di-（p-chloride benzylthio）-1,3-dithiole-2-thione.Compare and analyse the advantages and disadvantages of the two ways,and identify the structure with IR spectrum.