摘要
合成了第四周期过渡金属取代的Keggin结构钼磷、钨磷杂多化合物．讨论了合成条件，运用P－0键的IR振动变化表征了过渡金属离子电子组态的变化对缺位配体的修复作用．
The 4th period transition-metal lacunary monosubstituted molybdophosphoric and tungstophosphoric complexes with Keggin structrue were synthesized. The synthesis conditions were discussed. The repair effect of the changing of the transition- metal ions electronic configu-ration on the substituted ligands was characterizated by the vibration of P-O.
出处
《物理化学学报》
SCIE
CAS
CSCD
北大核心
1998年第5期435-438,共4页
Acta Physico-Chimica Sinica
基金
国家自然科学基金!29773016
关键词
KEGGIN结构
钼磷杂多化合物
钨磷杂多化合物
Transition-metal of the 4th period, Heteropoly complexes with Keggin structure, Lacunary monosubstitution, Vibration of P-O
