不对称五氮齿镉和铟大环配合物的合成及其光物理性质研究

SYNTHESIS OF ASYMMETRIC PENTAAZADENTATEMACROCYCLIC CADMIUM AND INDIUMCOMPLEXES AND THE STUDIES OF THEPHOTOPHYSICAL PROPERTIES

不对称五氮齿镉和铟大环配合物的合成及其光物理性质研究郭丰启孙文芳谢洁王夺元（中国科学院感光化学研究所，北京１００１０１）关键词不对称五氮齿金属配合物，电子吸收光谱，荧光１９９７年９月３日收到初稿，１９９７年１２月３０日收到修改稿．国家自然科学...

? In this paper, two new asymmetric pentaazadentate macrocyclic cadmium and indium complexes are synthesized and their electronic spectral properties including the molar extin ction coefficent(ε), the lifetimes of the first singlet excited state, the fluorescence quantum yield are measured. the experiments appear that these complexes exhibit an expanded optical window between the soret and the Q band in visible region and an H aggregation occurred in strong polar solvents.