类镓等电子序列ZrⅩ-RhⅩⅤ离子的4s^24p-4s^24d、4s^24p-4s4p^2、4s^24p-4s^25s、4p^3-4s^25s以及4s4p^2-4p^3跃迁谱线和振子强度的理论计算

THE CALCULATION OF TRANSITIONS 4s24p4s4p2, 4s24p4s25s,4s24p4s24d,4s4p24p3 and 4p34s25s ENERGY LEVELS, WAVELENGTHS AND OSCILLATOR STRENGTHES IN GaLIKE IONS FROM ZrXRhⅩⅤ

本文对类镓等电子序列ＧａⅠ—ＸｅⅩⅩⅠⅤ离子４ｓ２４ｐ、４ｓ２４ｄ、４ｓ４ｐ２、４ｐ３和４ｓ２５ｓ组态能级结构和组态相互作用进行了理论分析，找出沿等电子序列的变化规律。用作者提出的半经验公式［１］，内插预测了ＴｃⅩⅢ离子的４ｓ２４ｐ、４ｓ４ｐ２和４ｓ２５ｓ组态能级，外推预测了ＴｃⅩⅢ—ＲｈⅩⅤ离子的４ｐ３和４ｓ２４ｄ组态能级，并给出了４ｓ２４ｐ４ｓ２４ｄ、４ｓ２４ｐ４ｓ４ｐ２、４ｓ２４ｐ４ｓ２５ｓ、４ｐ３４ｓ２５ｓ和４ｓ４ｐ２—４ｐ３谱线波长和ＨＸＲ方法理论计算振子强度。用作者提出的半经验公式对组态能级的预测值与实验值的最大偏差小于１００ｃｍ－１。

In this paper,the 4s24p,4s24d,4s4p2,4p3 and 4s25s configuration′s energy level structures,and configuration interactions in GaLike from GaⅠ—Xe ⅩⅩⅣ ions are analysed in theory.The law of isoelectronic series is given.By using our fitted formula,the energies of TcⅩⅢ ion 4s24p,4s4p2 and 4s25s configurations are predicted by interpolation,the energies of TcⅢ Ⅹ—RhⅩⅤ ions 4p3 and 4s24d configurations are predicted by extrapolation.Wavelengths and oscillator strengthes(HXR theoretical calculation)of transitions 4s24p4s24d,4s24p4s4p2,4s24p4s25s,4p34s25s and 4s24p4p3 are given.The deviations of predictive energy levels from observed values are less than 100cm-1.