硝酸双-(1,10-二氮杂菲)苯乙酸锌(Ⅱ)配合物的合成和晶体结构

SYNTHESIS AND CRYSTAL STRUCTURE OF BIS(1,10PHENANTHROLINE) PHENYLACETATOZINC NITRATE

合成了标题化合物晶体。经Ｘ射线单晶结构分析确定该化合物晶体的化学结构式为［Ｚｎ（ｐｈｅｎ）２ＰＡＣ］ＮＯ３·２ＨＰＡＣ（ｐｈｅｎ＝１，１０－二氮杂菲，ＨＰＡＣ＝苯乙酸）。结构中Ｚｎ（Ⅱ）与一个苯乙酸和二个１，１０－二氮杂菲形成不规则八面体配合物，苯乙酸为双齿配位。

The title complex was synthesized The structural formula of the complex was confirmed as [Zn(phen)2(PAC)]NO3·HPAC(phen=1,10phenanthroline, HPAC=phenylacetic acid) by Xray analysis of single crystal The structure determination revealed that a Zn(Ⅱ) atom is bonded to two oxygen atoms from a phenylacetato group and four nitrogen atoms from two 1,10phenanthroline forming a distorted octahedron The complex belongs to triclinic, space group P1 with cell dimensions: a=10410(1),b=13773(1), c=16302(1); α=10405(1)°, β=10833(1)°, γ=8396(1)°, V=21512(6)3, Z=2 and R=0061, RW=0074