(Z)-1[2-(苯基二溴化锡基)乙烯基]-1-环己醇的合成及晶体结构

Synthesis and Crystal Structure of (Z)-1-[2-(pheny-Bibromide) vinyl]-1-Cyclohexanol

报道了标题化合物〔C14H18Br2OSn〕的合成及晶体结构。该晶体属于单斜晶系，空间点群为P21/c，晶胞参数a=11.711(2)，b=9．114（2），c=16．864（3）A，β=102.94（1）°，V=1604.55（0）A3，Mr=480．78，Z=4，Dc=1．99g／cm3，u=65．20cm－1，F（000）=919，R=0．050，Rw=0．050．晶体结构由直接法解出。标题化合物分子中的锡原子被配体的2个碳、2个溴和1个氧原子配位，配位原子呈畸变的三角双锥构型，环已基为椅式构象，五员杂环为信封构象。

Synthesis and crystal structure of the title compound are described. This crystal is monoclin-ic, space group P21/c with a=10. 710(2), b= 9. 114(2), c= 16. 864(3) A, β= 102. 94(1), V= 1604. 55(O) A 3 ,Z=4, Dc= 1. 99g/cm3, p=65. 20 cm-1, F(000) =919, R=0. 050, Rw=0. 050.The structure was solved by direct methods. The tin atom of the title molecule exists in adistorted-trigonal-bipyramidal geomctry defincd by two carbon, two bromide and ope oxygenatoms. Three carbon、one oxygen and onc tin atoms lcad to a fivc-mcmbcrcd chelate rjng. In thestructure, cyclohexanyl group has a chair conformation and the fivc-mcmbcrcd ring containingthe intermolecular O-Sn has a half chair con formation.