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三十六员八胺四酚大环配体的合成研究

Studies on synthesis of a 36-membered octaaminotetraphenol macrocyclic ligand
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摘要 对2,6-二甲酰基对甲苯酚与乙二胺进行[4+4]成环缩合的反应过程进行了研究,优化了实验条件,提高了合成产率。 The [ 4 ＋ 4 ] cyclocondensation reaction involving 2, 6 - Diformyl - 4 - methyl - phenol and 1, 2- diaminoethane was studied. Compared with the literature method, modification for the synthetic method led to improving the yield.
作者 徐强 宋仲容 何家洪 陈凤鸣
机构地区 重庆文理学院化学与环境工程学院
出处 《重庆文理学院学报（自然科学版）》 2009年第3期68-70,共3页 Journal of Chongqing University of Arts and Sciences
基金 重庆市教委科学技术研究项目(KJ071208) 重庆文理学院科研项目(Z2005HH12)
关键词 多胺 大环化合物 模板合成 polyamine macrocyclic complexes templated synthesis
分类号 O625 [理学—有机化学]
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参考文献7

  • 1Leonard F Lindoy, George V Meehan, Niels Svenstrup. Mono- and diformylation of 4 -substituted phenols: a new application of the duff reaction [ J ], SYNTHESIS, 1998,7 : 1029 - 1032.
  • 2Pilkington N H, Robson R. Complexes of binucleating ligands( Ⅲ )novel complexes of a macrocyclic binucleating ligand [ J ]. Australian Journal of Chemistry, 1970, 23(11):2225 - 2236.
  • 3Ishenkumba A Kahwa, Susan Folkes, Davide J Williams, et al. The first crystal and molecular structure of lanthanide homodinuclear macrocyclic complexes showing metal - metal pair interactions [ J ]. J Chem Soe Chem Commum, 1989: 1531.
  • 4Kausik K Nanda, Ramprasad Das, Michel J Newlands, et al. Phenoxo - bridged dinickel (Ⅱ) complexes of a macrocyclic ligand : synthesis, stereochemical equilibria and structure[ J]. J Chem Soc Dalton Trans, 1992, 5: 897 - 901.
  • 5Sasankasekhar Mohanta, Kausik K Nanda, Ruldiger Werner, et al. Macrocyclic Cu2^Ⅱ, Cu4^Ⅱ, Ni3^Ⅱ, and Ni4^Ⅱ complexes: magnetic properties of tetranuclear systems [J].Inorg Chem, 1997, 36 : 4656 - 4664.
  • 6Kausik K Nanda, Krishnan Venkatsubramanian, Devashis Majumdar, et al. Synthesis of a novel octaamino tetraphenol macrocyclic ligand and structure of a tetranuclear nickel(Ⅱ) complex [J]. Inorg Chem, 1994, 33:1581 - 1582.
  • 7徐强,宋仲容,陈凤鸣.2,6-二甲酰基-4-甲基苯酚合成方法的改进[J].西南民族大学学报（自然科学版）,2005,31(4):525-526. 被引量：2

二级参考文献10

  • 1Duncan C A, Copeland E P, Kahw a I A, et al. Unusual formation and crystal structure of a new stable dinuclear vanadium(V) amino-imino-acetal[J]. J Chem Soc, Dalton Trans,1997: 917.
  • 2Wang Z, Martell A E, Motekaitis R J, et al. Dinuclear Fe(Ⅱ) macrocyclic complexes as catalysts for theoxidation of hydrocarbons by molecular oxygen[J]. Inorg Chem Acta, 2000: 300-302, 378.
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  • 5Mohanta S, Nanda K K, Werner R, et al. Macrocyclic Cu^Ⅱ2, Cu^Ⅱ4, Ni^Ⅱ3, and Ni^Ⅱ4 complexes: magnetic properties of tetranuclear systems[J]. Inorg Chem, 1997, 36(21): 4656-4664.
  • 6Nanda K K, Venkatsubramanian K, Majumdar D, et al. Synthesis of a novel octaamino tetraphenol macrocyclic ligand and structure of a tetranuelear niekel(Ⅱ) comnlex[J]. Inorg Chem, 1994,33(8):1581-1582.
  • 7Gagne R R, Spiro C L, Smith T J, et al. The synthesis, redox properties, and ligand binding of heterobinuclear transition-metal macrocyclic ligand complexes. Measurement of an apparent delocalization energy in a mixed-valent Cu^ⅠCu^Ⅱ complex[J]. J Am Chem Soc, 1981, 103: 4073-4081.
  • 8Synthetic Communications[J]. 2000. 30(9): 1555-1561.
  • 9Verani C N, Rentschler E, Weyhermllller T, et al. Exchange coupling in a bis(heterodinuclear) [Cu^ⅡNi^Ⅱ]2 and a linear heterotrinuclear complex Co^ⅢCu^ⅡNi^Ⅱ. Synthesis, structures and properties[J]. J Chem Soc, Dalton Trans, 2000:251-258.
  • 10Lindoy L F, Meehan G V, Svenstrup N. Mono-and diformylation of 4-substituted phenols: A new application of the Duffreaction[J].synthesis, 1998, (7): 1029-1032.

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重庆文理学院学报（自然科学版）
2009年 第3期

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