摘要
The title compound [C4H12N2]3[PMo12O40] was synthesized from the hydrothermal reaction and charac- terized by IR, elemental analysis and X-ray signal crystal structural analysis. The crystal of the title complex belongs to trigonal space group R3c with a=1.788 62 nm, c=2.354 3 nm, and V=6.522 62 nm3, Z=6, R1=0.038 4, wR2 =0.102 0. The compound consisted of piperazine and PMo12O403 - , and the structure is extended to three dimensional framework owing to the hydrogen bond between the O atoms and N atoms. The bulk-modified carbon paste electrode (APM-CPE) using this compound as modifier shows a good electrocatalytic activity toward the oxidation of ascorbic acid(AA).
The title compound [CaH12N213[PMo12O40] was synthesized from the hydrothermal reaction and characterized by IR, elemental analysis and X-ray signal crystal structural analysis. The crystal of the title complex belongs to trigonal space group R3c with a=1.788 62 nm, c=2.354 3 nm, and V=6.522 62 nm^3, Z=6, R1=0.038 4, wR2 =0.102 0. The compound consisted of piperazine and PMo12O40^3-, and the structure is extended to three dimensional framework owing to the hydrogen bond between the O atoms and N atoms. The bulk-modified carbon paste electrode （APM-CPE） using this compound as modifier shows a good eleetrocatalytic activity toward the oxidation of ascorbic acid（AA）. CCDC： 707968.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2009年第6期1110-1114,共5页
Chinese Journal of Inorganic Chemistry
基金
吉林省科技发展计划项目资助(No.20071163)
关键词
水热合成
哌嗪
电化学性质
hydrothermal synthesis
piperazine
electrochemical properties
