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羧甲基纤维素接枝共聚制备多元高吸水性树脂 被引量:1

Synthesis of Multiple Super Absorbent Polymer through Graft Copolymerization of Carboxymethyl Cellulose
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摘要 高吸水性树脂(Super absorbent polymet.简称SAP)是一种含有强亲水性基团.并通常具有一定交联度的水溶胀型高分子聚合物,是20世纪60年代开始发展起来的新型功能高分子材料。高吸水性树脂的吸水量大、保水性强,即使在受热加压下也不易失水。随着经济的高速发展和环保意识的增强.高吸水性树脂的应用范围不断扩大.市场需求日益增加.研究开发也日趋活跃。 In this article, the graft copolymerization of acrylic acid, acrylamide and butyl methacrylate onto carboxymethyl cellulose is studied with the aim of synthesizing super absorbent polymer (SAP) , the main purpose is to improve absorbency of SAP by the cooperative action of different kinds of hydrophilic groups. Optimization of synthetic conditions is studied emphatically; and the structure of the product is characterized; besides, absorbency and water retention capability of SAP are also determined. According to the results of SEM, absorbency and water retention capability of SAP are improved greatly because of a lot of crevasse cracks, pores and bedded structure are appeared on the surface of the product. Many property-tests show that good absorbency and water retention capability of SAP are observed.
出处 《精细与专用化学品》 CAS 2009年第12期16-19,共4页 Fine and Specialty Chemicals
基金 "十一五"国家科技支撑计划项目(2006BAD18B10)
关键词 高吸水性树脂 羧甲基纤维素 接枝共聚 功能高分子材料 制备 高分子聚合物 亲水性基团 研究开发 carboxylmethyl cellulose vinyl monomer graft copolymerization SAP
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