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核磁共振方法研究工业级聚苯乙烯的热老化 被引量:2

Theraml Degradation Behaviors of PS Studied by NMR
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摘要 利用1H NMR,13C NMR方法,对2种工业级聚苯乙烯(EPS、HIPS)谱图进行了分析,找出了它们的特征信息;并对2样品进行了热老化模拟实验,得到了样品热老化时间与化学结构组成之间的变化规律。 Two kinds of industrial PS products (EPS,HIPS) were analyzed by using 1H, 13C NMR methods and their characteristic spectra were identified. The two products were then thermally degraded at different times followed by NMR analysis again to find out the relationship between heating aging time and the structural changes.
出处 《青岛科技大学学报(自然科学版)》 CAS 2009年第3期251-255,共5页 Journal of Qingdao University of Science and Technology:Natural Science Edition
关键词 聚苯乙烯 指纹结构 热老化 核磁共振 polystyrene fingerprint structure heating aging NMR
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  • 1杨军,刘景江.弹性体改性高抗冲聚苯乙烯的力学行为Ⅰ.拉伸和动态力学性能[J].高分子材料科学与工程,1995,11(2):71-75. 被引量:12
  • 2阎铁良.HIPS生产工艺及其专用橡胶简评[J].合成橡胶工业,1995,18(3):132-134. 被引量:5
  • 3杨慕杰,郑豪,赵健,沈之荃.稀土络合催化苯乙烯均聚及其与二乙烯苯共聚[J].高分子学报,1990(4):441-446. 被引量:4
  • 4复旦大学高分子教研室.高分子实验技术[M].上海:复旦大学出版社,1983..
  • 5蒋晓声.塑料中助剂的分析--选择分离、分析方案的探讨[J].高分子材料,1988,(1):2-2.
  • 6GEORGES M K, VEREGIN R P N, KAZMIZIER P M et al. Breathing new lift into the free radical polymerization process[ J].Macromoleeules, 1993,26:2 987.
  • 7CHIEFARI J, CHONG Y K, EROLE F et al. Living free-radical polymerization by reversible addition-fragmentation chain transfer: the RAFT process[ J]. Macromolecules, 1998,31:5 559.
  • 8JIN-SHAN WANG, KRZYSZTOF M. Controlled/"Living" radical polymerization. Atom transfer radical polymerization in the presence of transition-metal complexes[J]. Am Chem Soc, 1995,117:5 614.
  • 9VIRGIL P, BOGDAN B, ANDREAS N et al. Metal catalyzed "living" radical polymerization of styrenes initiated with arenesulfonyl chlorides. From heterogeneous to homogeneous catalysis[ J]. Macromolecules, 1996, 29:3 665.
  • 10WHITESIDE G M, SADOWSKI J S. Copper( I ) alkoxides, synthesis, reactions and thermal decomposition [J] .Am Chem Soc,1974,96:2 829.

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