氰基桥联配合物的溶剂热合成研究进展

Developments of solvothermal synthesis of cyano-bridged complexes

介绍了以MCN(M=Na,K)和K3[M′(CN)6](M′=Fe,Co)为氰基来源的氰基桥联配合物溶剂热合成的研究进展。讨论了影响溶剂热合成氰基桥联合物的主要因素,如:反应条件、有机配体、氰基来源、平衡离子、溶剂种类及摩尔比等.最后指出了目前存在的问题,并对今后的研究趋势进行了展望.

The recent progress of solvothermal synthesis of cyano-bridged complexes based on MCN（M = Na, K） and K3 [ M＇（ CN）6 ] （M＇ = Fe,Co） as the sources of cyano ligands was introduced in this paper. Then, the main factors influencing the solvothermal synthesis of cyano-bridged complexes were discussed, such as reaction conditions, organic ligands, cyano sources, counter-ions, solvents, molar ratio, and so on. Finally, the main problems at present were pointed, and the development trends were forecasted.