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The Phase Transition of Eu2O3 under High Pressures

The Phase Transition of Eu2O3 under High Pressures
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摘要 Pressure-induced phase transition of cubic Eu2 03 is studied by angle-dispersive x-ray diffraction (ADXD) up to 42.3 GPa at room temperature. A structural transformation from a cubic phase to a hexagonal phase is observed, which starts at 5.0 GPa and finishes at about 13.1 GPa. The phase transition leads to a volume collapse of 9.0% at 8.6 GPa. The hexagonal phase of Eu2 03 maintains stable up to the highest experiment pressure. After re/ease of pressure, the high-pressure phase transforms to a monoclinic phase. The pressure-volume data are fitted with the Birch-Murnaghan equation of state. The bulk moduli obtained upon compression from the fitting are 145(2) GPa and 151(6) OPa for the cubic and hexagonal phases, respectively, when their first pressure derivatives are fixed at 4. Pressure-induced phase transition of cubic Eu2 03 is studied by angle-dispersive x-ray diffraction (ADXD) up to 42.3 GPa at room temperature. A structural transformation from a cubic phase to a hexagonal phase is observed, which starts at 5.0 GPa and finishes at about 13.1 GPa. The phase transition leads to a volume collapse of 9.0% at 8.6 GPa. The hexagonal phase of Eu2 03 maintains stable up to the highest experiment pressure. After re/ease of pressure, the high-pressure phase transforms to a monoclinic phase. The pressure-volume data are fitted with the Birch-Murnaghan equation of state. The bulk moduli obtained upon compression from the fitting are 145(2) GPa and 151(6) OPa for the cubic and hexagonal phases, respectively, when their first pressure derivatives are fixed at 4.
出处 《Chinese Physics Letters》 SCIE CAS CSCD 2009年第7期215-217,共3页 中国物理快报(英文版)
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