摘要
通过2种途径合成了4-(三甲基硅基)苯乙炔(SPA)单体,采用核磁共振谱(NMR)和傅里叶变换红外光谱(FT-IR)进行了表征,在Pd(PPh3)2Cl2和金属共催化剂催化下制备了聚4-三甲基硅基苯乙炔poly(SPA)。探讨了聚合物的成膜性。
This article 4-trimethylsilylphenyl acetylene (SPA) monomer was synthesized through two schemeand, the monomer were characterized by the NMR and Fourier transform infrared spectroscopy (FT-IR). In Pd(PPh3)2Cl2 and metal catalysts poly SPA were prepared. Its a good film-forming.
出处
《齐齐哈尔大学学报(自然科学版)》
2009年第4期80-83,共4页
Journal of Qiqihar University(Natural Science Edition)
关键词
含硅基取代聚苯乙炔
聚合物制备
膜
containing silicon group substituted phenylacetylene
polymer prepare
membrane