镉(Ⅱ)与对乙酰氨基苯甲酸、4,4′-联吡啶配位聚合物的合成、晶体结构及荧光性质(英文)

Synthesis,Crystal Structure and Fluorescence Characterization of Cadmium(Ⅱ) Coordination Polymer with 4-Acetamidobenzoic Acid and 4,4'-Bipyridine

The complex {[Cd2(C9H8O3N)2(CH3COO)2(4,4'-bipy)2]·(4,4'-bipy)·(H2O)4}n with 4-acetamidobenzoic acid and 4,4'-bipyridine has been synthesized with liquid diffusion method and characterized. It crystallizes in the monoclinic space group C2/c. The crystal structure shows that two neighboring cadmium(Ⅱ) ions are linked together by two bridging acetic acid radicals,forming a binuclear structure. Adjacent binnuclear structure is linked together by two bridging 4,4'-bipy molecules and the complex molecule forms an one-dimensional doublechain structure. The luminescent properties of the complex were studied.

The complex {[Cd2（C9H8O3N）2（CH3COO）2（4,4′-bipy）2]· （4,4′-bipy）· （H2O）4}, with 4-aeetamidobenzoie acid and 4,4′-bipyridine has been synthesized with liquid diffusion method and characterized. It crystallizes in the monoclinic space group C2/c. The crystal structure shows that two neighboring cadmium （Ⅱ） ions are linked together by two bridging acetic acid radicals, forming a binuelear structure. Adjacent binnuclear structure is linked together by two bridging 4,4′-bipy molecules and the complex molecule forms an one-dimensional doublechain structure. The luminescent properties of the complex were studied. CCDC： 734878.