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Pt/三苯胺烯分子纳米复合物的制备及光催化作用

Preparation and photocatalysis of platinum/triphenylamine ethylene nanocomposite
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摘要 采用乙醇还原法制备了金属Pt/三苯胺烯共轭分子纳米复合物(Pt@DPSDA),通过UV-vis、TEM、FTIR、XRD、荧光、光电化学等方法对纳米复合物进行了表征。三苯胺烯分子通过分子末端羧基与金属Pt纳米粒子表面原子相互作用,形成以金属Pt纳米粒子为核,三苯胺烯分子为壳的核/壳型纳米复合物。光照下纳米复合物中激发态有机分子与金属Pt纳米粒子之间具有较好的电子转移作用,Pt@DPSDA纳米复合物可以作为催化剂在紫外-可见光照下分解水获得氢气。 Platinum/triphenylamine ethylene nanocomposite （Pt@ DPSDA） was prepared using an ethanol reduction method and characterized with UV-vis, TEM, FTIR, XRD, fluorescence spectroscopy, and photo-electrochemical method, respectively. Platinum core/conjugated organic molecule shell nanocomposite was formed as DPSDA molecules attached to the surface Pt atoms of platinum nanoparticles through carboxyl groups. DPSDA molecules in excited state may transfer photo-electron to the platinum nanoparticle. Under irradiation of UV-vis light, hydrogen was produced from photodecomposition of water using Pt@ DPSDA nanocompesite as the catalyst.
作者 程满环 朱明山 杜玉扣 杨平
机构地区 苏州大学材化部
出处 《化学研究与应用》 CAS CSCD 北大核心 2009年第7期998-1003,共6页 Chemical Research and Application
基金 国家自然科学基金(20673075)资助项目
关键词 三苯胺烯型分子 铂纳米复合物 光催化 氢气 triphenylamine ethylene derivative platinum nanocomposite photocatalysis hydrogen
分类号 O614.821 [理学—无机化学] O614.826 [理学—无机化学]
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参考文献21

  • 1Turner J A,Sustainable hydrogen production[J].Science,2004,305:972-974.
  • 2Gust D,Moore T A,Moore A L,Mimicking photosynthetic solar energy transduction[J].Acc.Chem.Res.,2001,34:40-48.
  • 3LaVan D A,Cha J N,Approaches for biological and biomimetic energy conversion[J].Proc.Natl.Acad.Sci.U.S.A.,2006,103:5251-5255.
  • 4Moradpour A,Amouyal E,Keller P,et al.Hydrogen production by visible light irradiation of aqueous solutions of Ru(bipy)32+[J].Nouv.J.Chim.,1978,2:547-549.
  • 5Chen Z P,Gunter M J,Gayness T P,et al.Photoinduced electron transfer in П-donor-capped Zn(II) porphyrins and N,N-dimethyl-4,4-bipyridinium supramolecular assemblies[J].J.Phys.Chem.B,1998,102:1159-1165.
  • 6Chakraborty S,Wadas T J,Hester H,et al.Platinum chromophore-based systems for photoinduced charge separation:a molecular design approach for artificial photosynthesis[J].Inorg.Chem.,2005,44:6865-6878.
  • 7Ozawa H,Haga M,Sakai K.A Photo-hydrogen-evolving Molecular device driving visible-light-induced EDTA-reduction of water into molecular hydrogen[J].J.Am.Chem.Soc.,2006,128:4926-4927.
  • 8李磊,程满环,杜玉扣,李宝宗,王筱梅,杨平.Pt/三苯胺酸卟啉酯纳米复合物的制备及光催化加氢反应[J].无机化学学报,2008,24(2):229-234. 被引量：1
  • 9Lambert C,Noll G.Intervalence charge-transfer bands in triphenylamine-based polymers[J].Synthetic Met.,2003,139:57-62.
  • 10Wang Z M,Wang X M,Zhao J F,et al.Cooperative enhancement of two-photon absorption based on electron coupling in triphenylamine-branching chromophore[J].Dyes Pigments,2008,79:145-152.

二级参考文献37

  • 1Roucoux A, Schulz J, Patin H. Chem. Rev., 2002,102:3757-3778.
  • 2Wan B, Liao Sh, Xu Y, et al. J. Mol. Catal. A: Chem., 1998, 136:263-268.
  • 3GAO Yan, WANG Fu-Dong , LIAO Shi-Jian, et al. Cuihua Xuebao(Chinese J. Catalysis), 1999,20(3):236-238.
  • 4MU Zhi-Gang, YANG Ping, DU Yu-Kou, et al. Shiyou Huagong(Petrochemical Technology),2002,31(10):795-798.
  • 5Du Yukou, Xu Jiaozheng, Yang Ping, et al. Colloids Surf. A :Physicochem. Eng., 2005,257-258:75-78.
  • 6Zhao M Q, Crooks R M. A ngew Chem., Int. Ed., 1999,38:364- 366.
  • 7Niu Y H, Yeung L K, Crooks R M. J. A m. Chem. Soc., 2001, 123:6840-6846.
  • 8Scott R W J, Wilson O M, Crooks R M. J. Phys. Chem. B,2005,109:692-704.
  • 9Rahim E H, Kamounah F S, Frederiksen J, et al. Nano Lett, 2001,1:499-501.
  • 10Gopidas K R, Whitesell J K, Fox M A. Nano Lett, 2003,3: 1757-1760.

共引文献4

化学研究与应用
2009年 第7期

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