摘要
目的：合成金属有机亚胺类化合物。方法：用二乙酰基二茂铁与卤代芳胺进行缩合反应，制备了七种卤代苯二茂铁双亚胺。结果：对所得化合物进行了元素分析，用红外光谱和核磁共振氢谱对化合物结构进行了表征。并探讨了卤素对缩合反应的影响。结论：卤素在芳环上的位置对缩合反应有比较大的影响。
Objective:To synthesize metal organic imines.Methods:Seven derivatives of 1.1-bis (1-(halogen arylimino)ethyl)-ferrocene were synthesized by condensation reaction from diacetyl ferrocene and halogen aromatic amine.Results:Their compositions and structures were confirmed by elementary analysis,IR and 1HNMR spectroscopy. The Schiff bases (3)～(7) and (1) are new compounds.Conclusion:The condensation reaction were affected by the position of halogen in the benzene nucleus.
出处
《内蒙古医学院学报》
1998年第2期93-95,共3页
Acta Academiae Medicinae Neimongol
基金
内蒙古自治区教育厅资助
关键词
卤代烃
卤代苯
二茂铁双亚胺
金属有机化合物
halohydrocarbon
halogeno-benzene ferrocene diimines
metal organic compounds
condensation reaction
