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手性多环化合物的Beckmann裂解反应研究 被引量：2

Study on Beckmann Fragmentation of Chiral Multi-ring Compounds
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摘要 手性Hajos酮的衍生物及甾体化合物经成肟,在PCl5/2,6-lutidine体系中进行Beckmann裂解反应,合成了四个系列的手性六环化合物。新化合物的结构经1HNMR,13CNMR,IR,MS和元素分析表征。 Four series of chiral hexacyclic compounds were synthesized by Beckmann fragmentation of Hajos ketone and steroid oxime derivatives in the presence of PCl5/2,6-lutidine. The structures were confirmed by ^1H NMR, ^13C NMR, IR, MS and elemental analysis.
作者 吴奇 祝曙英 晏昶皓 史海健
机构地区 南京工业大学化学化工学院
出处 《合成化学》 CAS CSCD 北大核心 2009年第4期397-404,共8页 Chinese Journal of Synthetic Chemistry
基金 国家自然科学基金资助项目(200771059) 江苏省高校自然科学基金资助项目(05KJB-150039)
关键词 Hajos酮衍生物 甾体 Beckmann裂解反应 合成 Hajos ketone derivative steroid Beckmann fragmentation synthesis
分类号 O625.42 [理学—有机化学] O621.3 [理学—有机化学]
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参考文献24

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同被引文献31

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引证文献2

合成化学
2009年 第4期

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