期刊文献+

低-中温下富锗闪锌矿的氧压酸浸研究(英文) 被引量:1

Low-and Medium-temperature Pressure Oxidation Leaching of Germanium-rich Sphalerite Concentrate
下载PDF
导出
摘要 通过正交试验对云南驰宏锌锗股份有限公司曲靖基地的富锗闪锌矿进行氧压酸浸研究。结果表明,在低温和中温下浸出动力学存在显著差异。在最佳试验条件(温度为150℃,氧分压为0.7MPa,浸出时间120min,物料粒度为58μm,搅拌速度为200r/min,酸锌比为1.4)下,锌和锗的浸出率分别为93.47%和89.84%。 The pressure oxidation leaching process of the germanium-rich sphalerite concentrate from Qujing-based Yunnan Chihong Zinc & Germanium Co. , Ltd is investigated by orthogonal experiments. Experimental resuhs demonstrate that there exists substantially kinetic difference between the two temperature ranges. The optimal condition is determined that leaching temperature 150℃, oxygen partial pressure 0.7 MPa, leaching duration 120min, grain size 58 μm, stirring rate 200r/min, acid-to-zinc molar ratio 1.4. The dissolutions of zinc and germanium with optimal parameters are 93.47% and 89. 84% , respectively.
出处 《有色金属》 CSCD 北大核心 2009年第3期62-70,共9页 Nonferrous Metals
基金 Scientific Research Foundation of Guangxi University(M313001)~~
关键词 冶金技术 闪锌矿 加压酸浸 正交实验 metallurgical technology sphalerite pressure acid leaching germanium orthogonal experiments
  • 相关文献

参考文献25

  • 1Harbuck D D. Gallium and germanium recovery from domestic sources [ R]. Washington, DC: Bureau of Mines, 1991 : 26 -33.
  • 2Bolorunduro S A, Dreisinger D B, Van Weert G. Zinc and silver recoveries from zinc-lead-iron complex sulphides by pressure oxidation [J]. Minerals Engineering, 2003, 16(4): 375-389.
  • 3Kun Huang, Qi-wei Li, Jing chen. Recovery of copper, nickel and cobalt from acidic pressure leaching solutions of low-grade sulfide flotation concentrate [J]. Minerals Engineering, 2007, 20(7): 722-728.
  • 4Aydogan S, Aras A, Canbazoglu M. Dissolution kinetics of sphalerite in acidic ferric chloride leaching [ J ]. Chemical Engineering Journal, 2005, 114( 1 - 3 ) : 67 - 72.
  • 5Toni Kaskiala. Determination of mass transfer between gas and liquid in atmospheric leaching of sulphidic zinc concentrate [ J ]. Minerals Engineering, 2005, 18 (12) : 1200- 1207.
  • 6Paul R Holmes, Frank K Crundwell. The kinetics of the oxidation of pyrite by ferric ions and dissolved oxygen: an electrochemical study [J]. Geochimica et Cosmochimica Acta, 2000, 64(2): 263-274.
  • 7Uhlig I, Szargan R, Nesbitt H W, et al. Surface states and reactivity of pyrite and marcasite [ J]. Applied Surface Science, 2001, 179(1 -4) : 222 -229.
  • 8Wilkin R T, Barnes H L. Pyrite formation by reactions of iron monosulfides with dissolved inorganic and organic sulfur species [J]. Geochimica et Cosmochimica Acta, 1996, 60(21) : 4167 -4179.
  • 9Weisener C G, Smart R St C, Gerson A R. Kinetics and mechanisms of the leaching of low Fe Germanium-rich sphalerite concentrate [ J]. Geochimica et Cosmochimica Acta, 2003, 67 (5) : 823 - 830.
  • 10Seyfried W E, Ding K. The effect of redox on the relative solubilities of copper and iron in Ct-bearing aqueous fluids at elevated temperatures and pressures: An experimental study with application to subseafloor hydrothermal systems [ J]. Geochimica et Cosmochimica Acta, 1993, 57(9) : 1905 - 1917.

同被引文献289

引证文献1

二级引证文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部